Advanced Chemistry of Materials

Credits: 3

Lecturers:

彭旭明（2/25, 3/4, 3/11）
林建村（3/18, 3/25, 4/1）
鄭淑芬（4/8, 4/15）
期中考（4/22）
呂光烈 (4/29, 5/6, 5/13）
陶雨台（5/20, 5/27）
陳錦地（ 6/3, 6/10, 6/17）
期末考（6/24）

Classroom: R201, Freshman Classroom Building, NTU

Outline:

(1)   Basic Concepts
Atomic Structure
Chemical Bonds
Lewis Structure
Molecular Orbital Theory
Special Topic: Metal-Metal Bonding

(2) Self-assembly of functional materials
Self-assembly and supramolecular chemistry
Supramolecular host-guest compounds
Metallacyclophanes
Molecular devices and sensors
Crystal engineering: Self-assembly, structure, and applications of metal-organic frameworks
Self-assembly of biomimetic materials

(3) Meso-porous Materials
Definition of “Nanoporous materials”
History
Structures and Characterization
Chemical Bonds & Self-assembly
Preparation of Nanoporous materials
Applications in Adsorbents, Catalysis, Nano-reactor, Guest-Host interaction etc

(4) Dye-Sensitized Solar Cell (DSC)
Structure and Mechanism of DSSC
Efficiency of DSSC
Dyes for DSSC
Nanoporous TiO2
Electrolytes for DSSC
Plastic PV Cell
Hybrided PV Cell

(5) Sensors
Principle of Sensing
Molecular Design for Recognition and Sensing
Ddendrimers and Polymers for Sensing
Application includeing Biosensors

(6) Organic Light-Emitting Diode (OLED) Materials
Development of OLED/LED
Comparison of OLED and Liquid Crystal Display (LCD)
Physical Principle of Devices
Properties of Light-Emitting Materials
Decaying issue of OLED
Efficiency of OLED, Fluorescence and Phosphorescence
Full Color OLED

(7) Organic Thin Films by self-assembly-Structure and applications
Langmuir Monolayers and Langmuir-Blodgett Multilayers
Self-Assembled Monolayers (SAMS)：
->Carboxylic acids on oxide surfaces
->Alkylsilanes on hydroxylated surfaces
->Organothiol on coinage metals
Mixed monolayers
Multilayers
Monolayer-protected clusters(MPCs)
Patterning of surfaces
->Soft lithography
->Dip-pen nanolithography
Sensor applications
Molecular electronics
Others

 

Grading:

Textbook:

Classnote:

Date	Topic
April 8, 2011	Prepapration, Applications and Structural Determination of Nano-porous Materials
April 15, 2011	Prepapration, Applications and Structural Determination of Nano-porous Materials (II)
April 19, 2011	Exam Samples